I-Catalyst
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I-catalyst yokushintsha kwezinga lokushisa eliphansi
I-catalyst yokushintsha kwezinga lokushisa eliphansi:
Isicelo
I-CB-5 ne-CB-10 isetshenziselwa Ukuguqulwa ekuhlanganiseni nasekukhiqizeni i-hydrogen izinqubo
Kusetshenziswa amalahle, i-naphtha, igesi yemvelo kanye negesi yasensimini kawoyela njengemithombo yokudla, ikakhulukazi kuma-axial-radial low lokushisa shift converters.
Izici
I-catalyst inezinzuzo zomsebenzi ekushiseni okuphansi.
Ukuminyana kwenqwaba ephansi, i-Copper ephakeme ne-Zinc surface namandla omshini angcono.
Izakhiwo zomzimba namakhemikhali
Uhlobo
CB-5
CB-5
I-CB-10
Ukubukeka
Amaphilisi amnyama angama-cylindrical
Ububanzi
5mm
5mm
5mm
Ubude
5mm
2.5mm
5mm
Ukuminyana ngobuningi
1.2-1.4kg/l
Amandla e-Radialcrushing
≥160N/cm
≥130 N/cm
≥160N/cm
I-CuO
40±2%
ZnO
43±2%
Izimo zokusebenza
Izinga lokushisa
180-260°C
Ingcindezi
≤5.0MPa
Isivinini sesikhala
≤3000h-1
I-Steam Gas Ratio
≥0.35
Faka i-H2Scontent
≤0.5ppmv
I-Inlet Cl-1okuqukethwe
≤0.1ppmv
I-ZnO desulfurization Catalyst enekhwalithi ephezulu kanye nentengo yokuncintisana
I-HL-306 isetshenziswa ekususeni i-sulfurization yamagesi aqhekeka ezinsalela noma ama-syngas kanye nokuhlanzwa kwamagesi okuphakelayo
izinqubo ze-organic synthesis. Ilungele kokubili izinga lokushisa eliphezulu (350–408°C) nangaphansi (150–210°c) ukusetshenziswa.
Ingakwazi ukuguqula isibabule semvelo esilula kuyilapho imunca isibabule esingaphili emgudwini wegesi. Ukusabela Main of the
inqubo desulfurization imi kanje:
(1) Ukusabela kwe-zinc oxide ne-hydrogen sulfide H2S+ZnO=ZnS+H2O
(2) Ukusabela kwe-zinc oxide ngezinye izinhlanganisela ezilula zesibabule ngezindlela ezimbili ezingenzeka.
2.Izakhiwo Zomzimba
Ukubukeka ama-extrudates amhlophe noma aphuzi Usayizi wezinhlayiya, mm Φ4×4–15 Ukuminyana ngobuningi, kg/L 1.0-1.3 3.Izinga Lekhwalithi
amandla okuchoboza, N/cm ≥50 ukulahlekelwa ekulahlekelweni, % ≤6 Umthamo wesibabule, wt% ≥28(350°C)≥15(220°C)≥10(200°C) 4. Isimo Esijwayelekile sokuSebenza
I-Feedstock: i-synthesis gas, igesi yenkundla kawoyela, igesi yemvelo, igesi yamalahle. Ingaphatha umfudlana wegesi ngesibabule esingaphili njengephezulu
njengo-23g/m3 enedigri yokuhlanza egculisayo. Ingase futhi ihlanze ukusakaza kwegesi kufika ku-20mg/m3 kokulula kangako
i-organic sulfur njenge-COS ukuya ngaphansi kuka-0.1ppm.
5.Iyalayisha
Ilayisha ukujula: I-L/D Ephakeme (min3) iyanconywa. Ukucushwa kwama-reactor amabili ochungechungeni kungathuthukisa ukusetshenziswa
ukusebenza kahle kwe-adsorbent.
Ilayisha inqubo:
(1)Hlanza i-reactor ngaphambi kokulayisha;
(2)Beka amagridi amabili angenabala anosayizi omncane we-mesh kune-adsorbent;
(3)Layisha ungqimba ongu-100mm we-Φ10—20mm wamaphanorama-refractory kumagridi angenabala;
(4)Skrini i-adsorbent ukuze ususe uthuli;
(5)Sebenzisa ithuluzi elikhethekile ukuqinisekisa ukusatshalaliswa ngokulinganayo kwe-adsorbent embhedeni;
(6)Hlola ukufana kombhede ngesikhathi sokulayisha. Lapho kudingeka ukusebenza kwangaphakathi kwereactor, Ipuleti lokhuni kufanele lifakwe kwi-adsorbent ukuze opharetha ame kulo.
(7)Faka Igridi engagqwali enosayizi omncane we-mesh kune-adsorbent kanye nongqimba oluyi-100mm lwe-Φ20—30mm refractory sphere phezulu kombhede we-adsorbent ukuze uvimbele ukungena kwe-adsorbent futhi uqinisekise.
ngisho nokusatshalaliswa komfudlana wegesi.
6.Ukuqala
(1)Shintsha uhlelo nge-nitrogen noma amanye amagesi angasebenzi kuze kube yilapho ukugcwala komoyampilo egesini kuba ngaphansi kuka-0.5%;
(2)Shisisa kuqala umfudlana wesiphakeli nge-nitrogen noma igesi yokuphakelayo ngaphansi kwengcindezi ezungezile noma ephakeme;
(3)Isivinini sokushisa: 50°C/h ukusuka kumazinga okushisa asekamelweni kuya ku-150°C (nge-nitrogen); 150°C amahora angu-2 (uma isisetshenziswa sokushisisa sinjalo
ishintshelwe kwigesi yokudla), 30°C/h ngaphezu kuka-150°C kuze kufike izinga lokushisa elidingekayo.
(4) Lungisa ingcindezi kancane kancane kuze kufinyelelwe ukucindezela kokusebenza.
(5) Ngemuva kokushisisa kwangaphambili nokuphakama komfutho, isistimu kufanele iqale isetshenziswe ngomthwalo oyingxenye amahora angu-8. Bese uphakamisa i
layisha kancane kancane lapho ukusebenza kuzinza kuze kube yilapho kusebenza ngokugcwele.
7.Vala
(1)Ukunikezwa kwegesi yokuvalwa okuphuthumayo (uwoyela).
Vala ama-valve angenayo kanye ne-outlet. Gcina izinga lokushisa nengcindezi.Uma kunesidingo, sebenzisa i-nitrogen noma i-hydrogen-nitrogen
igesi ukugcina ukucindezela ukuvimbela ukucindezela okubi.
(2) Ukuguqulwa kwe-adsorbent ye-desulfurization
Vala ama-valve angenayo kanye ne-outlet. Yehlisa kancane izinga lokushisa nokucindezela esimweni se-ambient. Bese wehlukanisa
i-desulfurization reactor evela ohlelweni lokukhiqiza. Faka esikhundleni i-reactor ngomoya kuze kube yilapho kutholakala umoya-mpilo ongaphezu kwama-20%. Vula i-reactor bese ukhulula i-adsorbent.
(3) Ukugcinwa kwezisetshenziswa (ukulungiswa kabusha)
Qaphela inqubo efanayo njengoba kukhonjisiwe ngenhla ngaphandle kokuthi ukucindezela kufanele kwehliswe ku-0.5MPa/10min kanye nezinga lokushisa.
kwehliswe ngokwemvelo.
I-adsorbent engalayishiwe izogcinwa izendlalelo ezihlukene. Hlaziya amasampula athathwe kusendlalelo ngasinye ukuze unqume
isimo kanye nempilo yesevisi ye-adsorbent.
8.Ezokuthutha kanye nesitoreji
(1) Umkhiqizo we-adsorbent upakishwe epulasitiki noma emiphongolweni yensimbi enolwelwesi lwepulasitiki ukuvikela umswakama kanye namakhemikhali.
ukungcola.
(2) Ukudilika, ukungqubuzana kanye nokudlidliza okunodlame kufanele kugwenywe ngesikhathi sokuthutha ukuze kuvinjelwe ukuguquguquka
i-adsorbent.
(3)Umkhiqizo we-adsorbent kufanele uvinjelwe ukuthintana namakhemikhali ngesikhathi sokuhamba nokugcinwa.
(4) Umkhiqizo ungagcinwa iminyaka emi-3-5 ngaphandle kokuwohloka kwezakhiwo zawo uma uvalwe ngokufanelekile.
Ukuze uthole imininingwane eyengeziwe mayelana nemikhiqizo yethu, sicela ungangabazi ukungithinta.
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I-Nickel Catalyst Njenge-Ammonia Ukubola I-Catalyst
I-Nickel Catalyst Njenge-Ammonia Ukubola I-Catalyst
I-ammonia decomposition catalyst iwuhlobo lwesekhondi. i-react catalyst, esekelwe ku-nickel njengengxenye esebenzayo ene-alumina njengomthwali oyinhloko. Isetshenziswa kakhulu esitshalweni se-ammonia se-reformer yesibili ye-hydrocarbon nokubola kwe-ammonia
idivayisi, isebenzisa i-hydrocarbon eyigesi njengempahla eluhlaza. Inokuqina okuhle, umsebenzi omuhle, namandla aphezulu.
Isicelo:
Isetshenziswa kakhulu esitshalweni se-ammonia se-reformer yesibili ye-hydrocarbon ne-ammonia yokubola,
usebenzisa i-gaseous hydrocarbon njengento eluhlaza.
1. Izakhiwo Zomzimba
Ukubukeka Indandatho ye-raschig empunga Usayizi we-particle, mmDiameter x Ubude x Ubukhulu 19x19x10 Amandla okuchoboza ,N/izinhlayiyana Ubuncane.400 Ukuminyana ngobuningi, kg/L 1.10 – 1.20 Ukulahlekelwa ekunciphiseni, wt% Ubukhulu.20 Umsebenzi we-Catalytic 0.05NL CH4/h/g I-Catalyst 2. Ukwakheka Kwamakhemikhali:
Okuqukethwe kwe-Nickel (Ni), % Okuncane.14.0 I-SiO2, % Ubukhulu.0.20 I-Al2O3, % 55 I-CaO, % 10 I-Fe2O3, % Ubukhulu.0.35 I-K2O+Na2O, % Ubukhulu.0.30 Ukumelana nokushisa:ukusebenza isikhathi eside ngaphansi kwe-1200 ° C, ukungancibiliki, okungancibiliki, okungaguquki, ukuqina okuhle kwesakhiwo namandla aphezulu.
Iphesenti lezinhlayiya zokuqina okuphansi (iphesenti elingaphansi kuka-180N/izinhlayiyana): max.5.0%
Inkomba yokumelana nokushisa: ukunganamatheli nokuphuka emahoreni amabili ku-1300°C
3. Isimo sokuSebenza
Izimo zenqubo Ingcindezi, MPa Izinga lokushisa, °C Isivinini sesikhala se-Amonia, hr-1 0.01 -0.10 750-850 350-500 Izinga lokubola kwe-ammonia 99.99% (amaminithi) 4. Impilo yesevisi: 2 iminyaka
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Ikhwalithi ephezulu ye-wholesale catalyst yemboni ye-hydrogenation
I-Hydrogenation industry catalyst
Nge-alumina njengesithwali, i-nickel njengengxenye eyinhloko esebenzayo, i-catalyst Isetshenziswa Kakhulu kupharafini wendiza kuya ku-hydrogenation dearomatization, benzene hydrogenation kuya ku-cyclohexane, i-phenol hydrogenation kuya ku-cyclohexanol hydrotreating, i-hydrofining ye-industrial crude hexane, kanye ne-organic-rated hydrogensphant hydrocarbonation ye-unsa. ama-hydrocarbon anephunga elimnandi, njengamafutha amhlophe, i-lube oil hydrogenation. Ingase futhi isetshenziselwe i-desulfurization yesigaba se-liquid ephumelelayo, kanye ne-sulfur protective agent enqubweni yokuguqula i-catalytic. I-catalyst inamandla aphezulu, umsebenzi omuhle kakhulu, enqubweni yokucwenga i-hydrogenation, engenza i-hydrocarbon enamakha noma engagcwalisiwe yehle iye ezingeni le-ppm. I-catalyst iyancipha isimo esizinzisa ukwelashwa.
Ngokuqhathanisa, i-catalyst esetshenziswe ngempumelelo ezitshalweni eziningi emhlabeni, ingcono kunemikhiqizo yasekhaya efanayo.
Izakhiwo zomzimba namakhemikhali:Into Inkomba Into Inkomba Ukubukeka isilinda esimnyama Ukuminyana ngobuningi ,kg/L 0.80-0.90 Usayizi wezinhlayiya, mm Φ1.8×-3-15 Indawo engaphezulu, m2/g 80-180 Izingxenye zamakhemikhali I-NiO-Al2O3 Amandla okuchoboza ,N/cm ≥ 50 Izimo zokuhlola umsebenzi:
Izimo Zenqubo Ingcindezi yesistimu
MpaI-Hydrogen Nitrogen space velocity hr-1 Izinga lokushisa
°CIsivinini se-Phenol isikhala
hr-1Isilinganiso se-hydrogen phenol
mol/molIngcindezi evamile 1500 140 0.2 20 Ileveli Yomsebenzi I-Feedstock: i-phenol, ukuguqulwa kwe-phenol min 96% Ukuze uthole imininingwane eyengeziwe mayelana nemikhiqizo yethu, sicela ukhululeke ukuxhumana nami.